One-Pot Synthesis of Styrene Derivatives from Allyl Silanes via B(C6F5)3-Catalyzed Isomerization – Hiyama Coupling: data

Herein we report a one-pot synthesis of styrene derivatives via a novel B(C₆F₅)₃-catalyzed E-selective isomerization of readily accessible allyl silanes and subsequent Hiyama coupling of the versatile alkenyl silane intermediates. This one-pot two-step approach enables access to a broad range of styrene derivatives including those containing Lewis basic functional groups that are inaccessible via the previously developed B(C₆F₅)₃-catalyzed isomerization of allyl benzenes.

Analysis of reaction products from this methodology resulted in the following data:

1H, 19F and 13C NMR raw data files

IR spectra

High resolution mass spectrometry spectra.

Research results based upon these data are published at https://doi.org/10.1021/acs.orglett.2c03584