Manganese-Catalyzed One-Pot Conversion of Nitroarenes into N-Methylarylamines Using Methanol - data

<p>A manganese-catalyzed one-pot conversion of nitroarenes into <em>N</em>-methylarylamines has been developed. This transfer hydrogenation method employs a well-defined bench stable Mn PN³P pincer precatalyst in combination with methanol as both the reductant and the C1 source. A selection of commercially available nitroarenes was converted into <em>N</em>-methylarylamines in synthetically useful yields.</p><p>Analysis of reaction products from this methodology resulted in the following data:</p><p>1H, 19F and 13C NMR raw data files</p><p>IR spectra</p><p>High resolution mass spectrometry spectra.    </p><p>Research results based upon these data are published at http://doi.org/10.1002/ejoc.201901854<br></p>