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B(3,4,5-F3H2C6)3 Lewis acid-catalysed C3-allylation of indoles: data

dataset

posted on 2024-09-18, 11:39 authored by Nusaybah AlotaibiNusaybah Alotaibi, Rasool Babaahmadi, Milan PramanikMilan Pramanik, Tanja KaehlerTanja Kaehler, Ayan DasguptaAyan Dasgupta, Emma RichardsEmma Richards, Alireza Ariafard, Thomas WirthThomas Wirth, Rebecca MelenRebecca Melen

Herein we report the B(3,4,5-F3H2C6)3-catalysed C3-allylation of indoles using allylic esters. 25 examples of C3-allylated products are presented in up to 97% yield. The mechanism for the reaction was explored using detailed Density Functional Theory (DFT) studies. The data includes experimental procedures, NMR spectra and DFT outputs.

Research results based upon these data are published at https://doi.org/10.1039/D3DT00745F

Funding

Activating diazo compounds with boranes in flow (2022-09-02 - 2024-09-01); Melen, Rebecca. Funder: Royal Society

From Organic to Inorganic Chemistry: Exploiting the Isolobal Analogy to Develop Main Group Catalysts

Engineering and Physical Sciences Research Council

Find out more...

Single or Double? A radical approach to synthesis via frustrated Lewis Pairs (2020-06-01 - 2025-01-15); Richards, Emma. Funder: The Leverhulme Trust:RPG-2020-16

History

Data-collection start date

2021-04-01

Data-collection end date

2023-04-01

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Keywords

Acid/base Catalysis

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CC BY 4.0

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