1,3-Carboboration of iodonium ylides

Herein, we disclose the utilisation of iodonium ylides to access a range of boron dienolates. Heating of acyclic iodonium ylides in the presence of different aryl boranes leads to the formation of rare 1,3-carboboration products. This methodology could not be expanded to cyclic iodonium ylides which instead formed a Lewis acid–base adduct. Products proved to be remarkably stable under a wide range of conditions allowing for their long term storage.

The data included consists of experimental proscdures, characterisation (NMR data) and X-ray data.

Research results based upon these data are published at https://doi.org/10.1039/C9CC08749D